Singer Alicia Keys will launch her fifth album ‘Girl On Fire’ at the MTV Video Music Awards. Keys, 31, will sing the album`s title track at the award ceremony to be held here Sep 6, reports a website. The album will be released Nov 27 and feature collaborations with singers Jeff Bhasaker, Gary Clarke Jr and Emeli Sande. However, the single will be available for online download via iTunes from Sep 4. Keys recorded the album while travelling the world and she spent time in studios in London, Jamaica and New York.